Summary: A completely updated, expanded edition of a longstanding and influential text on chemical thermodynamics Covers the logical foundations and interrelationships of thermodynamics and their application to problems that are commonly encountered by the chemist. Explanations of abstract concepts in a clear and simple, yet still rigorous fashion Logical arrangement of the material to facilitate learning, including worked out examples. Computational techniques, graphical, numerical, and anal
ytical, are described fully and are used frequently, both in illustrative and in assigned problems.
Summary: A completely updated, expanded edition of a longstanding and influential text on chemical thermodynamics Covers the logical foundations and interrelationships of thermodynamics and their application to problems that are commonly encountered by the chemist. Explanations of abstract concepts in a clear and simple, yet still rigorous fashion Logical arrangement of the material to facilitate learning, including worked out examples. Computational techniques, graphical, numerical, and analytical, are described fully and are used frequently, both in illustrative and in assigned problems. ...show less
Edition/Copyright:7TH 08 Cover: Print On Demand Publisher:John Wiley & Sons, Inc. Published: 06/03/2008 International: No
View Author Bio
Robert M. Rosenberg is Emeritus Professor of Chemistry at Lawrence University and an Adjunct Professor of Chemistry at Northwestern University.
View Table of Contents
1 INTRODUCTION. 1.1 Origins of Chemical Thermodynamics. 1.2 Objectives of Chemical Thermodynamics. 1.3 Limitations of Classic Thermodynamics. References.
2 MATHEMATICAL PREPARATION FOR THERMODYNAMICS. 2.1 Variables of Thermodynamics. Extensive and Intensive Quantities. Units and Conversion Factors. 2.2 Analytic Methods. Partial Differentiation. Exact Differentials. Homogeneous Functions. Exercises. References 3 THE FIRST LAW OF THERMODYNAMICS. 3.1 Definitions. Temperature. Work. 3.2 The First Law of Thermodynamics. Energy. Heat. General Form of the First Law. Exercises. References.
4 ENTHALPY, ENTHALPY OF REACTION, AND HEAT CAPACITY. 4.1 Enthalpy. Definition. Relationship between Q v and Q p . 4.2 Enthalpy of Reactions. Definitions and Conventions. 4.3 Enthalpy as a State Function. Enthalpy of Formation from Enthalpy of Reaction. Enthalpy of Formation from Enthalpy of Combustion. Enthalpy of Transition from Enthalpy of Combustion. Enthalpy of Conformational Transition of a Protein from Indirect Calorimetric Measurements. Enthalpy of Solid-State Reaction from Measurements of Enthalpy of Solution. 4.4 Bond Enthalpies. Definition of Bond Enthalpies. Calculation of Bond Enthalpies. Enthalpy of Reaction from Bond Enthalpies. 4.5 Heat Capacity. Definition. Some Relationships between C p and C v . Heat Capacities of Gases. Heat Capacities of Solids. Heat Capacities of Liquids. Other Sources of Heat Capacity Data. 4.6 Enthalpy of Reaction as a Function of Temperature. Analytic Method. Arithmetic Method. Graphical or Numerical Methods. Exercises. References.
5 APPLICATIONS OF THE FIRST LAW TO GASES. 5.1 Ideal Gases. Definition. Enthalpy as a Function of Temperature Only. Relationship Between C p and C v . Calculation of the Thermodynamic Changes in Expansion Processes. 5.2 Real Gases. Equations of State. Joule-Thomson Effect. Calculations of Thermodynamic Quantities in Reversible Expansions. Exercises. References.
6 THE SECOND LAW OF THERMODYNAMICS. 6.1 The Need for a Second Law. 6.2 The Nature of the Second Law. Natural Tendencies Toward Equilibrium. Statement of the Second Law. Mathematical Counterpart of the Verbal Statement. 6.3 The Carnot Cycle. The Forward Cycle. The Reverse Cycle. Alternative Statement of the Second Law. Carnot's Theorem. 6.4 The Thermodynamic Temperature Scale. 6.5 The Definition of S, the Entropy of a System. 6.6 The Proof that S is a Thermodynamic Property. Any Substance in a Carnot Cycle. Any Substance in Any Reversible Cycle. Entropy S Depends Only on the State of the System. 6.7 Entropy Changes in Reversible Processes. General Statement. Isothermal Reversible Changes. Adiabatic Reversible Changes. Reversible Phase Transitions. Isobaric Reversible Temperature Changes. Isochoric Reversible Temperature Changes. 6.8 Entropy Changes in Irreversible Processes. Irreversible Isothermal Expansion of an Ideal Gas. Irreversible Adiabatic Expansion of an Ideal Gas. Irreversible Flow of Heat from a Higher Temperature to a Lower Temperature. Irreversible Phase Transitions. Irreversible Chemical Reactions. General Statement. 6.9 General Equations for the Entropy of Gases. Entropy of the Ideal Gas. Entropy of a Real Gas. 6.10 Temperature-Entropy Diagram. 6.11 Entropy as an Index of Exh
2008 Hardcover Good NO CD; No Access Code; Minor highlighting, markings and tears; Some edge, cover, corner wear, scratches and creases; Unless stated otherwise herein the notes, complementary boo...show moreks or items are not present; $20.00 minimum excluding shipping for orders to Puerto Rico & Hawaii; standard shipping is by USPS Media Mail & Expedited shipping is by USPS Priority Mail or equivalent; ...show less
Free Shipping Get Free Shipping on orders over $25 (not including Rental and Marketplace). Order arrives in 5-10 business days.
Need it faster? We offer fast, flat-rate expedited shipping options.
Not the right book for you? We'll gladly take it back within 30 days.
To return an eTextbook:
Your eTextbook is non-returnable once it's been activated. You must contact us about returning your eTextbook before you activate it.
Returns are accepted within 30 days of the purchase date on your order confirmation.
This book qualifies for guaranteed cash back! Buy it now for , then:
Sell it back by:
Guaranteed cash back:
Cost of this book after cash back:
Take advantage of Guaranteed Cash Back. Send your book to us in good condition before the end of the buyback period, we'll send YOU a check, and you'll pay less for your textbooks!
If you find this book for less on Amazon.com (direct from Amazon, not marketplace sellers), we'll match it.
In our warehouse, waiting to ship directly to you.
We hand-inspect every used textbook to make sure it's in good condition.
Buy it now. Sell it later!
Sell this textbook for cash!
When you're done with this book, sell it back to Textbooks.com. In addition to the best possible buyback price, you'll get an extra 10% cash back just for being a customer.
We buy good-condition used textbooks year 'round, 24/7. No matter where you bought it, Textbooks.com will buy your textbooks for the most cash.
We hand-inspect every one of our used textbooks to ensure good condition.
Our used textbooks do NOT have:
Missing or torn pages
Missing or torn cover
Torn or damaged binding
A broken spine
This textbook has never been used.
Due to the size of eTextbooks, a high-speed internet connection (cable modem, DSL, LAN) is required for download stability and speed. Your connection can be wired or wireless.
Being online is not required for reading an eTextbook after successfully downloading it. You must only be connected to the Internet duringthe download process.
XP or Windows 7 (32 or 64 running in 32 bit mode), or Mac OS 10.6 or above
At least 512 MB RAM, 600 mHZ processor, and 40 MB of hard drive space (75MB for Mac OS)
What is the Marketplace? It's another way for you to get the right price on the books you need. We approved every Marketplace vendor to sell their books on Textbooks.com, so you know they're all reliable.
What are Marketplace shipping options? Marketplace items do not qualify for free shipping. When ordering from the Marketplace, please specify whether you want the seller to send your book Standard ($3.99/item) or Express ($6.99/item). To get free shipping over $25, just order directly from Textbooks.com instead of through the Marketplace.
FREE UPS 2nd Day Air Terms
Rental and Marketplace items are excluded. Offer is valid from 1/21/2013 12:00PM to 1/23/2013 11:59AM CST. Your order must be placed by 12 Noon CST to be processed on the same day. Minimum order value is $100.00 excluding Rental and Marketplace items. To redeem this offer, select "FREE UPS 2ND DAY AIR" at checkout. Offer not is not valid on previous orders.