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Edition: 5TH 94

Copyright: 1994

Publisher: John Wiley & Sons, Inc.

Published: 1994

International: No

Copyright: 1994

Publisher: John Wiley & Sons, Inc.

Published: 1994

International: No

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Uses the classical (phenomenological) approach to thermodynamics as opposed to the statistical. Applies theory to chemical, biological and geological problems. Provides complete coverage of essential mathematical tools and computational techniques. This edition contains new chapters on thermodynamics of the electrochemical cell, Eh/pH diagrams, a revised chapter on estimation of thermodynamic properties plus treatment of the latest work in electrolyte solutions. Additional problems reflect new applications.

**Mathematical Preparation for Thermodynamics Enthalpy, Enthalpy of Reaction, and Heat Capacity Application of the First Law to Gases The Second Law of Thermodynamics Equilibrium and Spontaneity for Systems at Constant Temperature: The Free Energy Functions Application of the Gibbs Free Energy Function to Some Phase Changes The Third Law of Thermodynamics Application of the Gibbs Free Energy Function to Chemical Changes Thermodynamics of Systems of Variable Composition Mixtures of Gases The Ideal Solution Dilute Solutions of Nonelectrolytes Activities and Standard States for Nonelectrolytes Calculation of Partial Molar Quantities from Experimental Data: Volume and Enthalpy Determination of Nonelectrolyte Activities Activity, Activity Coefficients, and Osmotic Coefficients of Strong Electrolytes **Index

Summary

Uses the classical (phenomenological) approach to thermodynamics as opposed to the statistical. Applies theory to chemical, biological and geological problems. Provides complete coverage of essential mathematical tools and computational techniques. This edition contains new chapters on thermodynamics of the electrochemical cell, Eh/pH diagrams, a revised chapter on estimation of thermodynamic properties plus treatment of the latest work in electrolyte solutions. Additional problems reflect new applications.

Table of Contents

**Mathematical Preparation for Thermodynamics Enthalpy, Enthalpy of Reaction, and Heat Capacity Application of the First Law to Gases The Second Law of Thermodynamics Equilibrium and Spontaneity for Systems at Constant Temperature: The Free Energy Functions Application of the Gibbs Free Energy Function to Some Phase Changes The Third Law of Thermodynamics Application of the Gibbs Free Energy Function to Chemical Changes Thermodynamics of Systems of Variable Composition Mixtures of Gases The Ideal Solution Dilute Solutions of Nonelectrolytes Activities and Standard States for Nonelectrolytes Calculation of Partial Molar Quantities from Experimental Data: Volume and Enthalpy Determination of Nonelectrolyte Activities Activity, Activity Coefficients, and Osmotic Coefficients of Strong Electrolytes **Index

Publisher Info

Publisher: John Wiley & Sons, Inc.

Published: 1994

International: No

Published: 1994

International: No

**Mathematical Preparation for Thermodynamics Enthalpy, Enthalpy of Reaction, and Heat Capacity Application of the First Law to Gases The Second Law of Thermodynamics Equilibrium and Spontaneity for Systems at Constant Temperature: The Free Energy Functions Application of the Gibbs Free Energy Function to Some Phase Changes The Third Law of Thermodynamics Application of the Gibbs Free Energy Function to Chemical Changes Thermodynamics of Systems of Variable Composition Mixtures of Gases The Ideal Solution Dilute Solutions of Nonelectrolytes Activities and Standard States for Nonelectrolytes Calculation of Partial Molar Quantities from Experimental Data: Volume and Enthalpy Determination of Nonelectrolyte Activities Activity, Activity Coefficients, and Osmotic Coefficients of Strong Electrolytes **Index