ISBN13:978-0138419172 ISBN10: 0138419175 Edition/Copyright:3RD 99 Cover: Hardback Publisher:Prentice Hall, Inc. Published: 08/12/1998 International: No
View Author Bio
Lehman, John W.: Lake Superior State University
View Table of Contents
Preface. To the Instructor. Introduction. Laboratory Safety.
I. MASTERING THE OPERATIONS.
1. Learning Basic Operations. The Effect of pH on a Food Preservative. 2. Extraction and Evaporation. Separating the Components of Panacetin. 3. Recrystallization and Melting Point Measurement. Identifying a Constituent of Panacetin. 4. Heating under Reflux. Synthesis of Salicyclic Acid from Wintergreen Oil. 5. Simple Distillation, Gas Chromatography. Preparation of Synthetic Banana Oil. 6. Fractional Distillation. Separation of Petroleum Hydrocarbons. 7. Addition, Mixing, Sublimation. Preparation of Camphor. 8. Boiling Point, Refractive Index. Identification of a Petroleum Hydrocarbon. 9. Column Chromatography, UV-VIS Spectrometry. Isolation and Isomerization of Lycopene from Tomato Paste. 10. Steam Distillation, Infrared Spectrometry. Isolation and Identification of the Major Constituent of Clove Oil. 11. Thin-Layer Chromatography, NMR Spectrometry. Identification of Unknown Ketones. 12. Vacuum Distillation, Optical Rotation. Optical Activity of a-Pinene.
II. CORRELATED LABORATORY EXPERIMENTS.
13. Investigation of a Chemical Bond by Infrared Spectrometry. 14. Properties of Common Functional Groups. 15. Thin-Layer Chromatographic Analysis of Drug Components. 16. Separation of an Alkane Clathrate. 17. Isomers and Isomerization Reactions. 18. Structures and Properties of Stereoisomers. 19. Bridgehead Reactivity in an SN1 Solvolysis Reaction. 20. Reaction of Iodoethane with Sodium Saccharin, an Ambident Nucleophile. 21. Dehydration of Methylcyclohexanols. 22. Synthesis of 7,7-Dichloronorcarane Using a Phase-Transfer Catalyst. 23. Stereochemistry of the Addition of Bromine to trans-Cinnamic Acid. 24. Hydration of a Difunctional Alkyne. 25. Preparation of Bromotriphenylmethane and the Trityl Free Radical. 26. Chain-Growth Polymerization of Styrene and Methyl Methacrylate. 27. Synthesis of Ethanol by Fermentation. 28. The Reaction of Butanols with Hydrobromic Acid. 29. Borohydride Reduction of Vanillin. 30. Multistep Synthesis of Cyclopentanol from Cyclohexanol. 31. Synthesis of Triphenylmethanol and the Trityl Carbocation. 32. Identification of a Conjugated Diene from Eucalyptus Oil. 33. Spectral Identification of Terpenoids. 34. Synthesis and Spectral Analysis of Aspirin. 35. Preparation of Nonbenzenoid Aromatic Compounds. 36. Mechanism of the Nitration of Arenes by Nitronium Fluoborate. 37. Friedel-Crafts Acylation of Anisole. 38. Structure of a Natural Product in Anise Oil. 39. Identification of an Oxygen-Containing Organic Compound. 40. Wittig Synthesis of 1,4-Diphenyl-1,3-Butadiene. 41. Effect of Reaction Conditions on the Condensation of Furfural with Cyclopentanone. 42. Haloform Oxidation of 4'-Methoxyacetophenone. 43. Electronic Effect of a para-Iodo Substituent. 44. Synthesis and Identification of an Unknown Carboxylic Acid. 45. Preparation of the Insect Repellent N, N-Diethyl-m-Toluamide. 46. Synthesis of 2-Acetylcyclohexanone by the Stork Enamine Reaction. 47. Synthesis of Dimedone and Measurement of Its Tautomeric Equilibrium Constant. 48. Preparation of Para Red and Related Azo Dyes. 49. Reaction of Phthalimide with Sodium Hypochlorite. 50. Identification of an Unknown Amine. 51. Preparation and Mass Spectrum of 2-Phenylindole. 52. Nucleophilic Strength and Reactivity in SNAr Reactions. 53. Structure of an Unknown D-Hexose. 54. Fatty Acid Content of Commercial Cooking Oils. 55. Structure of an Unknown Dipeptide. 56. Multistep Synthesis of Benzilic Acid from Benzaldehyde. 57. Using the Chemical Literature in an Organic Synthesis. 58. A Research Project in Organic Chemistry.
1. Making Useful Laboratory Items. 2. Extraction of Iodine by Dichloromethane. 3. Purification of an Unknown Compound by Recrystallization. 4. Developing and Testing a Hypothesis. 5. Preparation of Acetate Esters. 6. Gas Chromatographic Analysis of Commercial Xylene. 7. Isolation of Caffeine from No-Doz Tablets. 8. A Missing Label Puzzle. 9. Paper Chromatography of Dyes in Commercial Drink Mixes. 10. Gas Chromatographic Analysis of an Essential Oil from Orange Peel. 11. Identification of an Unknown Felt-Tip Pen Ink by TLC. 12. Optical Rotation of Turpentine. 13. The Structures of Organic Molecules. 14. Who Else Has My Compound? 15. Isomers and Molecular Structure. 16. Reactivities of Alkyl Halides in Nucleophilic Substitution Reactions. 17. An SN1 Reaction of Bromotriphenylmethane. 18. Preparation and Properties of a Gaseous Alkene. 19. Addition of Iodine to a-Pinene. 20. Unsaturation in Commercial Products. 21. Free-Radical Bromination of Hydrocarbons. 22. The Nylon Rope Trick. 23. Nucleophilic Substitution Rates of Alcohols. 24. Photoreduction of Benzophenone to Benzopinacol. 25. Oxidation of Alcohols by Potassium Permanganate. 26. Preparation of a Fluorescent Dye. 27. Diels-Alder Reaction of Maleic Anhydride and Furan. 28. Identification of an Unknown Arene by NMR Spectrometry. 29. Interpretation of a Mass Spectrum. 30. Nitration of Naphthalene. 31. Preparation of Trityl Cations by the Friedel-Crafts Reaction. 32. Air Oxidation of Fluorene to 9-Fluorenone. 33. A Nucleophilic Addition-Elimination Reaction of Benzil. 34. Preparation of Aldol Condensation Products. 35. A Spontaneous Reaction of Benzaldehyde. 36. Acid/Base Strengths of Organic Compounds. 37. Hydrolysis Rates of Esters. 38. Preparation of Benzamide. 39. Synthesis of Dimedone Derivatives of Benzaldehyde. 40. A Diazonium Salt Reaction of 2-Aminobenzoic Acid. 41. Beckmann Rearrangement of Benzophenone Oxime. 42. Dyeing with Indigo. 43. Reaction of Monosaccharides with Phenols. 44. Extraction of Trimyristin from Nutmeg. 45. Preparation of a Soap Using a Phase-Transfer Catalyst. 46. Isolation of Protein from Milk.
IV. QUALITATIVE ORGANIC ANALYSIS.
An Overview of Qual Organic. Preliminary Work. Classification. Spectral Analysis. Identification. Exercises.
V. THE OPERATIONS.
1. Cleaning and Drying Glassware. 2. Using Standard-Taper Glassware. 3. Using Glass Rod and Tubing. 4. Weighing. 5. Measuring Volume. 6. Heating. 7. Cooling. 8. Temperature Monitoring. 9. Mixing. 10. Addition of Reactants. 11. Gravity Filtration. 12. Vacuum Filtration. 13. Extraction. 14. Evaporation. 15. Steam Distillation. 16. Column Chromatography. 17. Thin-Layer Chromatography. 18. Paper Chromatography. 19. Washing Liquids. 20. Drying Liquids. 21. Drying Solids. 22. Drying and Trapping Gases. 23. Recrystallization. 24. Sublimation. 25. Simple Distillation. 26. Vacuum Distillation. 27. Fractional Distillation. 28. Melting Point. 29. Boiling Point. 30. Refractive Index. 31. Optical Rotation. 32. Gas Chromatography. 33. High Performance Liquid Chromatography. 34. Infrared Spectrometry. 35. Nuclear Magnetic Resonance Spectrometry. 36. Ultraviolet-Visible Spectrometry. 37. Mass Spectrometry.
I. Laboratory Equipment. II. Keeping a Laboratory Notebook. III. Writing a Laboratory Report. IV. Calculations for Organic Synthesis. V. Planning an Experiment. VI. Properties of Organic Compounds. VII. The Chemical Literature.
A book with obvious wear. May have some damage to the cover or binding but integrity is still intact. There might be writing in the margins, possibly underlining and highlighting of text, but no missi...show moreng pages or anything that would compromise the legibility or understanding of the text. ...show less
$1.99 +$3.99 s/h
Goodwill Industries Miami, FL
Acceptable Used-Acceptable May have slight wear, may contain some highlighting or writing-we try to only select the highest quality used books.
$1.99 +$3.99 s/h
Clean Earth Books Atlanta, GA
Fair FREE TRACKING/DELIVERY CONFIRMATION ON ALL ORDERS! ! A used book that may have some cosmetic wear (i.e. shelf-wear, slightly torn or missing dust jacket, dented corner...) All text in great sha...show morepe! Ships Safe, Secure, & Fast! 100% MONEY BACK GUARANTEE! ...show less
$2.04 +$3.99 s/h
Goodwill Industries South Florida Fort Lauderdale, FL
Used - Acceptable May have slight wear, may contain some highlighting or writing-we try to only select the highest quality used books
$2.75 +$3.99 s/h
Arch Reads Florissant, MO
1998 Hardcover Fair *Condition Acceptable a book with obvious wear. May have some damage to the cover but integrity still intact. The binding may be slightly damaged but integrity is still intact....show more Possible writing in margins, possible underlining and highlighting of text, but no missing pages or anything that would compromise the legibility or understanding of the text. See the seller's listing for full details and description of any imperfections. ...show less
$5.00 +$3.99 s/h
Textbookcenter.com Columbia, MO
Ships same day or next business day via UPS (Priority Mail for AK/HI/APO/PO Boxes)! Used sticker and some writing and/or highlighting. Used books may not include working access code or dust jacket.
$17.95 +$3.99 s/h
omgtextbooks Pueblo West, CO
Upper Saddle River, NJ 1998 Hard cover 3rd ed. Good. Sewn binding. Cloth over boards. 808 p.
$35.50 +$3.99 s/h
Books Revisited Chatham, NJ
Possible retired library copy, some have markings or writing. May or may not include accessories such as CD or access codes.
Free Shipping Get Free Shipping on orders over $25 (not including Rental and Marketplace). Order arrives in 5-10 business days.
Need it faster? We offer fast, flat-rate expedited shipping options.
Not the right book for you? We'll gladly take it back within 30 days.
To return an eTextbook:
Your eTextbook is non-returnable once it's been activated. You must contact us about returning your eTextbook before you activate it.
Returns are accepted within 30 days of the purchase date on your order confirmation.
This book qualifies for guaranteed cash back! Buy it now for , then:
Sell it back by:
Guaranteed cash back:
Cost of this book after cash back:
Take advantage of Guaranteed Cash Back. Send your book to us in good condition before the end of the buyback period, we'll send YOU a check, and you'll pay less for your textbooks!
If you find this book for less on Amazon.com (direct from Amazon, not marketplace sellers), we'll match it.
In our warehouse, waiting to ship directly to you.
We hand-inspect every used textbook to make sure it's in good condition.
Buy it now. Sell it later!
Sell this textbook for cash!
When you're done with this book, sell it back to Textbooks.com. In addition to the best possible buyback price, you'll get an extra 10% cash back just for being a customer.
We buy good-condition used textbooks year 'round, 24/7. No matter where you bought it, Textbooks.com will buy your textbooks for the most cash.
We hand-inspect every one of our used textbooks to ensure good condition.
Our used textbooks do NOT have:
Missing or torn pages
Missing or torn cover
Torn or damaged binding
A broken spine
This textbook has never been used.
Due to the size of eTextbooks, a high-speed internet connection (cable modem, DSL, LAN) is required for download stability and speed. Your connection can be wired or wireless.
Being online is not required for reading an eTextbook after successfully downloading it. You must only be connected to the Internet duringthe download process.
XP or Windows 7 (32 or 64 running in 32 bit mode), or Mac OS 10.6 or above
At least 512 MB RAM, 600 mHZ processor, and 40 MB of hard drive space (75MB for Mac OS)
What is the Marketplace? It's another way for you to get the right price on the books you need. We approved every Marketplace vendor to sell their books on Textbooks.com, so you know they're all reliable.
What are Marketplace shipping options? Marketplace items do not qualify for free shipping. When ordering from the Marketplace, please specify whether you want the seller to send your book Standard ($3.99/item) or Express ($6.99/item). To get free shipping over $25, just order directly from Textbooks.com instead of through the Marketplace.
FREE UPS 2nd Day Air Terms
Rental and Marketplace items are excluded. Offer is valid from 1/21/2013 12:00PM to 1/23/2013 11:59AM CST. Your order must be placed by 12 Noon CST to be processed on the same day. Minimum order value is $100.00 excluding Rental and Marketplace items. To redeem this offer, select "FREE UPS 2ND DAY AIR" at checkout. Offer not is not valid on previous orders.