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Summary: Chemists use this resource to gain a more conceptual understanding of reaction mechanisms. The tenth edition has been revised to make the content even more accessible as it explores the fundamentals of organic chemistry. New Solved Problems have been added to reinforce the concepts. Bulleted lists are included to highlight important topics and definitions. Additional bond-line drawings and ball-stick models have also been added. Chemists will appreciate these changes ...show more as the book continues its tradition of excellence in preparing them for success. ...show lessEdition/Copyright: 10TH 11
T.W. Graham Solomons did his undergraduate work at the Citadel and received his doctorate in organic chemistry in 1959 from Duke University where he worked with C.K. Bradsher. Following this he was a Sloan Foundation Postdoctoral Fellow at the University of Rochester where he worked with V. Boekelheide. In 1960 he became a charter member of the faculty of the University of South Florida and became Professor of Chemistry in 1973. In 1992 he was made Professor Emeritus. In 1994 he was a visiting professor with the Faculty des Sciences Pharmaceutiques et Biologiques, Universite Rene Descartes (Paris V). He is a member of Sigma Xi, Phi Lambda Upsilon, and Sigma Pi Sigma. He has received research grants from the Research Corporation and the American Chemical Society Petroleum Research Fund. For several years he was director of an NSF-sponsored Undergraduate Research Participation Program at USF. His research interests have been in the areas of heterocyclic chemistry and unusual aromatic compounds. He has published papers in the Journal of the American Chemical Society, the Journal of Organic Chemistry, and the Journal of Heterocyclic Chemistry. He has received several awards for distinguished teaching. His organic chemistry textbooks have been widely used for 20 years and have been translated into French, Japanese, Chinese, Korean, Malaysian, Arabic, Portuguese, Spanish, Turkish, and Italian. He and his wife Judith have a daughter who is a building conservator, a son who is an artist, and another son who is a graduate student studying biochemistry.
Craig Barton Fryhle is Chair and Professor of Chemistry at Pacific Lutheran University. He earned his B.A. degree from Gettysburg College and Ph.D. from Brown University. His experiences at these institutions shaped his dedication to mentoring undergraduate students in chemistry and the liberal arts, which is a passion that burns strongly for him. His research interests have been in areas relating to the shikimic acid pathway, including molecular modeling and NMR spectrometry of substrates and analogues, as well as structure and reactivity studies of shikimate pathway enzymes using isotopic labeling and mass spectrometry. He has mentored many students in undergraduate research, a number of whom have later earned their Ph.D. degrees and gone on to academic or industrial positions. he has participated in workshops on fostering undergraduate participation in research, and has been an invited participant in efforts by the National Science Foundation to enhance undergraduate research in chemistry. He has received research and instrumentation grants from ten National Science Foundation, the M.J Murdock Charitable Trust, and other private foundations.
His work in chemical education, in addition to textbook co-authorship, involves incorporation of student-let teaching in the classroom and technology-based strategies in organic chemistry.
He has also developed experiments for undergraduate students inorganic laboratory and instrumental analysis courses. He has been a volunteer with the hands-on science program in Seattle public schools, and chair of the Puget Sound Section of the American Chemical Society. He lives in Seattle with his wife and two daughters.
Table of Contents
Ch. 1 Carbon Compounds and Chemical Bonds 1
Ch. 2 Representative Carbon Compounds: Functional Groups, Intermolecular Forces, and Infrared (IR) Spectroscopy 52
Ch. 3 An Introduction to Organic Reactions: Acids and Bases 94
Ch. 4 Alkanes: Nomenclature, Conformational Analysis, and an Introduction to Synthesis 134
Ch. 5 Stereochemistry: Chiral Molecules 193
Ch. 6 Ionic Reactions - Nucleophilic Substitution and Elimination Reactions of Alkyl Halides 238
Ch. 7 Alkenes and Alkynes I: Properties and Synthesis, Elimination Reactions of Alkyl Halides 287
Ch. 8 Alkenes and Alkynes II: Addition Reactions 328
Ch. 9 Nuclear Magnetic Resonance and Mass Spectrometry: Tools for Structure Determination 383
Ch. 10 Radical Reactions 447
Ch. 11 Alcohols and Ethers 492
Ch. 12 Alcohols from Carbonyl Compounds. Oxidation-Reduction and Organometallic Compounds 537
Ch. 13 Conjugated Unsaturated Systems 577
Ch. 14 Aromatic Compounds 622
Ch. 15 Reactions of Aromatic Compounds 664
Ch. 16 Aldehydes and Ketones I. Nucleophilic Addition to the Carbonyl Group 716
Ch. 17 Aldehydes and Ketones II. Aldol Reactions 769
Ch. 18 Carboxylic Acids and Their Derivatives. Nucleophilic Addition - Elimination at the Acyl Carbon 813
Ch. 19 Synthesis and Reactions of [Beta]-Dicarbonyl Compounds: More Chemistry of Enolate Ions 878
Ch. 20 Amines 840
Ch. 21 Phenols and Aryl Halides: Nucleophilic Aromatic Substitution 1000
Ch. 22 Carbohydrates 1072
Ch. 23 Lipids 1128
Ch. 24 Amino Acids and Proteins 1166
Ch. 25 Nucleic Acids and Protein Synthesis 1220
Answers to Selected Problems
Photo and Illustration Credits
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